Very old school. Called a blocking diode, and that is indeed what you would do if you didn't have a charge controller between the panel and the battery. Probably the first diode application for the first panel was a blocking diode. The downside is the forward voltage drop over the diode, which is why you don't want one.
You could, but if you found a voltage that would not be proof positive that there was any significant current - open circuit voltage on a length of wire can be a tricky thing. You have your energy meter set up to monitor discharge, which is how you would install it to monitor load and detect naughty loads. So, monitor the load. Remove YOUR load at night and your meter should show zero amps. If it does not, you MIGHT be back bleeding through the controller, pull the positive panel wire off the controller. If it is still reading amps, pull the positive battery wire off the controller. If it is still reading amps you have a bad wiring job. Now, if you have an ammeter, nothing wrong with plugging that between the panel and controller, or between the controller and battery at night. Oh wait - that is where your energy meter is, look at it...
To check the chinesium CC should I check voltage on the panel side after dark?
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