What does "choke" mean?
An isolated run of wire, without the return current wire nearby, will have a calculable inductance. This will vary with the size and length of the wire.
If you curve the wire into one or more loops the inductance increases.
If you wind the wire around an iron (or magnetic steel alloy) core, the inductance goes up a whole lot.
Now for the tricky part. If you run a piece of wire through a ferrous metal conduit, that is for practical purposes the same as winding a partial turn of wire through an iron core. That means that at the range of frequencies present in a lightning even (including a near strike), the presence of the raceway will greatly increase the impedance of the GEC.
To avoid this, we let the high frequency currents flow in the conduit itself (via the bonding jumpers at both ends), so the magnetic field is outside the "core" and does cause a large inductance in the length of conduit.
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